materialsscienceandengineering:
Is this the battery breakthrough we’ve been longing for?Aluminum “Yolk-and-Shell” Nanoparticle Boosts Capacity and Power of Lithium-ion Batteries
New research from MIT and Tsinghua University in China reveals that an aluminum “yolk-and-shell” nanoparticle could boost the capacity and power of lithium-ion batteries.Read more.
One big problem faced by electrodes in rechargeable batteries, as they go through repeated cycles of charging and discharging, is that they must expand and shrink during each cycle — sometimes doubling in volume, and then shrinking back. This can lead to repeated shedding and reformation of its “skin” layer that consumes lithium irreversibly, degrading the battery’s performance over time.
Now a team of researchers at MIT and Tsinghua University in China has found a novel way around that problem: creating an electrode made of nanoparticles with a solid shell, and a “yolk” inside that can change size again and again without affecting the shell. The innovation could drastically improve cycle life, the team says, and provide a dramatic boost in the battery’s capacity and power.
The new findings, which use aluminum as the key material for the lithium-ion battery’s negative electrode, or anode, are reported in the journal Nature Communications, in a paper by MIT professor Ju Li and six others. The use of nanoparticles with an aluminum yolk and a titanium dioxide shell has proven to be “the high-rate champion among high-capacity anodes,” the team reports.
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